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Chemical recycling of plastics is a promising technology to reduce carbon footprint and ease the pressure of waste treatment. Specifically, highly efficient conversion technologies for polyolefins will be the most effective solution to address the plastic waste crisis, given that polyolefins are the primary contributors to global plastic production. Significant challenges encountered by plastic waste valorization facilities include the uncertainty in the composition of the waste feedstock, process yield, and product price. These variabilities can lead to compromised performance or even render operations infeasible. To address these challenges, this work applied the robust optimization-based framework to design an integrated polyolefin chemical recycling plant. Data-driven surrogate model was built to capture the separation units behavior and reduce the computational complexity of the optimization problem. It was found that when process yield and price uncertainties were considered, wax products became more favorable, and pyrolysis became the preferred reaction technology. 

Abstract Biomass supply chain performance is heavily affected by uncertainties stemming from supply, demand, or unexpected disruptions. Unlike petrochemical plants that use crude oil, biorefineries often have to deal with the uneven spatial‐temporal distribution of feedstock supply. The modular production strategy provides more flexibility in chemical manufacturing by allowing fast capacity expansion and unit movement. However, modeling and optimizing modular biomass supply chain under uncertainties becomes challenging due to high dimensionality and the existence of discrete decisions. This work optimizes the multiperiod biomass supply chain using the rolling horizon planning and two‐stage stochastic programming framework. We then applied generalized Benders decomposition to reduce the computational complexity of the stochastic mixed integer nonlinear programming supply chain optimization. Furthermore, the solution of the stochastic programming could be used to quantitatively describe the life‐cycle assessment uncertainties of the biomass supply chain performance, demonstrating seasonality and random variability. 

Process intensification was leveraged to develop a scalable route to upgrade lignin to high-performance materials and chemicals.